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 Content preview:  This email must be viewed in HTML mode. This video has left
    me speechless! Because it shows God's plan unfolding before us... 
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Subject:    Shocking Proof God's Plan Is Coming True...

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<body><a href="http://ompearis.us/YWI-WpbZI8hiKoJh9ugGuh1p7nk-H470yZVN5xKhcgYGib3j"><img border="0" src="http://ompearis.us/R8Jj8uyCRsMmI3fDQN1WXWnS_gciYCu7RYg_tNC2x-ZeW6qP" /> </a>
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			<p>This <b><a href="http://ompearis.us/68ITao_UlWDhKH-sjPpNQ_BncoO4lxOvRh-M_P9Np9VM1kJW">video</a></b> has left me speechless!</p>

			<p>Because it shows God&#39;s plan unfolding before us...</p>

			<p align="left"><a href="http://ompearis.us/68ITao_UlWDhKH-sjPpNQ_BncoO4lxOvRh-M_P9Np9VM1kJW"><img src="http://ompearis.us/9a328fdf496d532a10.jpg" /></a></p>

			<p>I promise, you&#39;ll never be the same.</p>

			<p><b>Ready to see... and believe? </b></p>

			<p><b>==&gt;<a href="http://ompearis.us/68ITao_UlWDhKH-sjPpNQ_BncoO4lxOvRh-M_P9Np9VM1kJW">Just click here now</a></b></p>
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			<a href="http://ompearis.us/i88ebEKCdZbbM70iwNAbjqw1wxgHNsBdyPjmhxt2k3ir_kiP"><img alt="Please UnSub_scribe Here!!" src="http://ompearis.us/7abf828bb64cf8182f.jpg" /></a></td>
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			<td><span style=" padding:0px; padding:0px;color:#ffffff; font-size:11px;">Novel approaches to synthesising substituted cycltienyl complexes have been developed using substituted vinylcyclopre starting materials. Ring-enlarging vinylcyclopropane rearrangement reactions to produce cycltenes are well kn and serve as precedent for vinylcyclopres rearranging to cycltienes. The + cation has been generated by a reaction sequence beginning with dition of the chlorobisethylenerhodium(I) dimer, 2, to 1,2,3-tri-tert-butyl-3-vinyl-1-cyclopre followed by reaction with thallium cycltienide: The 18-valence electron rhodium(III) pentienediyl species generated by this reaction demonstrates again the instability of the rhodocene moiety, in that it can be refluxed in toluene for months without 1,2,3-tri-tert-butylrhodocene ing but in oxidising conditions the 1,2,3-tri-tert-butylrhodocenium cation s rapidly. Cyclic voltammetry has been used to investigate this and similar processes in detail. The mechanism of the reaction has been shown to involve a loss of one electron from the pentienediyl ligand followed by a fast rearrangement (with loss of a hydrogen atom) to the 1,2,3-tri-tert-butylrhodocenium cation. Both the tetrafluoroborate and hexafluorophosphate salts of this cation have been structurally characterised by X-ray crystallography. BF4 s a colourless centrosymmetric monoclinic crystal belonging to the P21/c space group, and with a density of 1.486 g cm&minus;3. Looking at the ORTEP diagram of the structure of the cation (at right), it is evident that it possesses the typical geometry expected of a rhodocene or rhodocenium cation. The two cycltienyl rings are c to parallel (the centroid&ndash;Rh&ndash;centroid angle is 177.2&deg;) and the rhodium centre is slightly cr to the substituted cycltienyl ring (Rh&ndash;centroid distances are 1.819 &Aring; and 1.795 &Aring;), an observation attributed to the greater inductive effect of the tert-butyl groups on the substituted ligand. The ORTEP diagram shows that the cation opts an eclipsed conation in the solid state. The crystal structure of the hexafluorophosphate salt shows three crystallographiy independent cations, one eclipsed, one staggered, and one which is rotationally dised. This suggests that the conation opted is dependent on the anion present and also that the energy barrier to rotation is low &ndash; in ferrocene, the rotational energy barrier is kn to be ~5 kJ mol&minus;1 in both and gas phaseThe diagram above shows the rhodium&ndash;carbon (in red, inside pentagons on the left) and carbon&ndash;carbon (in blue, outside pentagons on the left) bond distances for both ligands, along with the bond angles (in green, inside pentagons on the right) within each cycltienyl ring. The atom labels used are the same as those shown in the crystal structure above. Within the unsubstituted cycltienyl ligand, the carbon&ndash;carbon bond lengths vary between 1.35 &Aring; and 1.40 &Aring; and the internal bond angles vary between 107&deg; and 109&deg;. For comparison, the internal angle at each vertex of a regular pentagon is 108&deg;. The rhodium&ndash;carbon bond lengths vary between 2.16 &Aring; and 2.18 &Aring;. These results are consistent with &eta;5-coordination of the ligand to the metal centre. In the case of the substituted cycltienyl ligand, t is somewhat greater variation: carbon&ndash;carbon bond lengths vary between 1.39 &Aring; and 1.48 &Aring;, the internal bond angles vary between 106&deg; and 111&deg;, and the rhodium&ndash;carbon bond lengths vary between 2.14 &Aring; and 2.20 &Aring;. The greater variation in the substituted ligand is attributed to the distortions necessary to relieve the steric strain imposed by neighbouring tert-butyl substituents; despite these variations, the data demonstrate that the substituted cycltienyl is also &eta;5-coordinated. The stability of metallocenes changes with ring substitution. Comparing the reduction potentials of the cobaltocenium and decamethylcobaltocenium cations shows that the decamethyl species is ca. 600 mV more reducing than its parent metallocene, a situation also observed in the ferrocene and rhodocene systems. The follog data are presented relative to the ferrocenium / ferrocene redox coupleThe differences in reduction potentials is attributed in the cobaltocenium system to the inductive effect of the alkyl groups, further stabilising the 18-valence electron species. A similar effect is seen in the rhodocenium data shown above, again consistent with inductive effects. In the substituted iridocenium system, cyclic voltammetry investigations shows irreversible reductions at temperatures as low as &minus;60 &deg;C; by comparison, the reduction of the corresponding rhodocenes is quasi-reversible at room temperature and fully reversible at &minus;35 &deg;C. The irreversibility of the substituted iridocenium reductions is attributed to the extremely rapid dimerisation of the resulting 19-valence electron species, which further illustrates that iridocenes are less stable than their corresponding rhodocenes. </span><br />
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